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With the rapid development of LED lighting, lasers, and optical communication technologies, higher requirements are being placed on encapsulation materials in terms of light transmittance, refractive index matching, and thermal stability. Phenyltrimethoxysilane (PTMS), with its relatively high refractive index (around 1.54) and excellent transparency, has become an important raw material for optical-grade silicone materials.
Conventional methyl siloxanes typically have a refractive index of about 1.40–1.43, making it difficult to match GaN chips (~2.4) or glass optical fibers (~1.46). The phenyl group introduced by PTMS possesses high electronic polarizability, enabling silicone resins to achieve refractive indices above 1.50. This effectively reduces interfacial reflection losses and improves light extraction efficiency. In high-power LED encapsulation, this directly translates into higher luminous efficiency and lower junction temperatures.
At the same time, PTMS-modified silicone materials exhibit excellent resistance to yellowing under UV exposure and high temperatures, maintaining long-term transparency and ensuring consistent lighting quality. In optical fiber coatings, PTMS also enhances mechanical buffering performance and resistance to heat and humidity, protecting fiber cores from micro-bending losses.
From household LED packages to high-speed optical modules used in 5G data centers, PTMS plays a crucial role in ensuring efficient light transmission and stable optical performance.